Dissolve 3 Tbs sugar in the hot coffee. Then add the orange peels and vanilla. Let the mixture cool down and refrigerate while you make the cheese mixture.
Separate the yolks from the whites. In a medium bowl, beat the yolks with the remaining 3 Tbs sugar until the sugar is dissolved. Add the cheese and beat until well incorporated and the mixture becomes smooth and lighter in color (I did it by hand, but you can use an electric mixer)
In the clean bowl of a stand up mixer, whisk the egg whites until they become opaque and hold stiff, glossy peaks.
Gently fold the egg whites into the cheese mixture. Refrigerate for about 30 minutes.
Spread 3 Tbs cheese mixture evenly in the bottom of the ceramic dish. One by one, dip the ladyfingers in the coffee mixture and arrange them in one layer. Cover with 1/2 of the mascarpone mixture, spreading evenly. Using a small colander, dust with cocoa powder and scatter some of the blakberries. Repeat this process with one more layer of ladyfingers and finish with the last 1/2 of the mascarpone mixture. Dust with a good amount of cocoa powder and arrange the remaining blackberries on top. Refrigerate until ready to eat.
Notes
Use espresso or strongly brewed coffee
The tiramisu will keep in the refrigerator for up to 3 days